可见光不对称催化 光诱导手性合成核心试剂组合
2026-10-13 · 推荐产品 · 百灵威授权转载
可见光不对称催化是手性合成领域的新兴热门方向，利用可见光激发催化剂引发反应，条件温和、绿色环保、官能团兼容性好，可实现诸多传统热反应难以完成的转化，广泛应用于复杂天然产物、手性药物及功能分子的创新研发。有机光催化剂结合手性协同助剂的体系，是实现高对映选择性可见光反应的主流方案。
为助力客户布局前沿光催化研发方向，我们精选多种高品质可见光催化剂与手性协同助剂，重磅推出可见光不对称催化核心试剂组合。套装覆盖吖啶盐类有机光催化剂、铱配合物等光催化剂，搭配多种手性酸、手性配体作为协同助剂，可灵活适配不同类型的可见光不对称反应。全系列产品纯度优异、批次稳定性强，一站式满足光催化手性合成核心试剂需求，助力前沿研发高效推进。
光催化剂
| 品名 | CAS | 货号 |
|---|---|---|
| 9-Mesityl-10-methylacridinium perchlorate, 98% 9-均三甲苯基-10-甲基吖啶高氯酸盐 | 674783-97-2 | 627185 |
| 9-Mesityl-10-methylacridinium tetrafluoroborate, 97% 9-基三甲苯基-10-甲基吖啶鎓四氟硼酸盐 | 1442433-71-7 | 2337723新 |
| 10-Methyl-9-phenylacridinium perchlorate, 98% 10-甲基-9-苯基吖啶高氯酸盐 | 36519-61-6 | 627186新 |
| (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[[5-trifluoromethyl-2-pyridinyl-kappaN)phenyl-kappaC]iridium(III) Hexafluorophosphate, 95% (4,4'-二叔丁基-2,2'-联吡啶)双[3,5-二氟-2-[[5-三氟甲基-2-吡啶基-κN]苯基-κC]铱(III)六氟磷酸盐 | 870987-63-6 | 1866865 |
| [Ir(dtbbpy)(ppy)2]PF6, 97% (4,4'-二叔丁基-2,2'-联吡啶)双[(2-吡啶基)苯基]铱(III)六氟磷酸盐 | 676525-77-2 | 1836092 |
| (2,2'-Bipyridine)bis[3,5-difluoro-2-[[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99% （2,2'-联吡啶）双[3,5-二氟-2- [[5-三氟甲基-2-吡啶基-kN]苯基-kC]六氟磷酸铱（III），99％ | 1092775-62-6 | 77-0453促 |
| Tris(2-phenylpyridine)iridium, 99%, for synthesis 三(2-苯基吡啶)合铱 | 94928-86-6 | 997766 |
| Tris(2,2'-bipyridyl)ruthenium(II)chloride hexahydrate, 98% 三(2,2’-联吡啶基)氯化钌(II)六水合物 | 50525-27-4 | 102033 |
| Tris(2,2'-bipyridine)ruthenium(II) bis(hexafluorophosphate), 98% 三(2,2'-联吡啶)钌(II)二(六氟磷酸)盐 | 60804-74-2 | 988227 |
| Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium (II) dichloride 三( 4,7-联苯-1,10-邻菲啰啉)二氯化钌 | 36309-88-3 | 241557 |
手性酸类
| 品名 | CAS | 货号 |
|---|---|---|
| (+)-10-Camphorsulfonic acid, 99% (+)-10-樟脑磺酸 | 3144-16-9 | 485835 |
| (-)-10-Camphorsulfonic acid, 99% (-)-10-樟脑磺酸 | 35963-20-3 | 154661 |
| (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate, 98% (S)-(+)-1,1'-联萘-2,2'-二基磷酸氢酯 | 35193-64-7 | 109345 |
| (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate, 98% (R)-(-)-联萘酚膦酸酯 | 39648-67-4 | 996635 |
| (S)-(+)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate, 96% (S)-3,3'-双(三苯甲硅烷基)-1,1'-联萘-2,2'-二酚磷酸酯 | 929097-92-7 | 1476982 |
| (R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate, 96% (R)-(-)-3,3'-双(三苯甲硅烷基)-1,1'-联萘-2,2'-二酚膦酸氢酯 | 791616-55-2 | 789137 |
| L-(+)-Tartaric acid, 99.5% L-(+)-酒石酸 | 87-69-4 | 245105 |
| D-(-)-Tartaric acid, 99% D-(-)-酒石酸 | 147-71-7 | 122583 |
| D-(+)-Camphoric acid, 99% D-(+)-樟脑酸 | 124-83-4 | 355552 |
| (1S)-(-)-Camphanic acid, 98% (1S)-(-)-莰烷酸 | 13429-83-9 | 129536 |
手性配体类
| 品名 | CAS | 货号 |
|---|---|---|
| (S)-(-)-1,1'-Bi-2,2'-naphthol, 99% (S)-(-)-1,1'-联萘-2,2'-二酚 | 18531-99-2 | 465318 |
| (R)-(+)-1,1'-Bi-2,2'-naphthol, 99% (R)-(+)-1,1'-联萘-2,2'-二酚 | 18531-94-7 | 465317 |
| (R)-2-Methyl-CBS-oxazaborolidine, 97% (R)-2-甲基-CBS-恶唑硼烷 | 112022-83-0 | 913741 |
| (S)-(-)-2-Methyl-CBS-oxazaborolidine, 1.0 M solution in THF (S)-(-)-2-甲基-CBS-噁唑硼烷 | 112022-81-8 | 107724 |
| Quinidine, 83% 奎尼丁 | 56-54-2 | 272633 |
| Quinine, 97%, for synthesis 奎宁 | 130-95-0 | 938232 |
| Cinchonidine, 98.5% 辛可尼丁 | 485-71-2 | 232996 |
| Cinchonine, 95% 辛可宁 | 118-10-5 | 287282 |
相关产品
超干溶剂
| 品名 | CAS | 货号 |
|---|---|---|
| Tetrahydrofuran, 99.9%, SuperDry, stabilized with 250 ppm BHT, Water≤50 ppm, J&KSeal 四氢呋喃 | 109-99-9 | 315353促 危化品 |
| Acetonitrile, 99.9%, SuperDry, with molecular sieves, water≤50 ppm, J&KSeal 乙腈 | 75-05-8 | 939631促 危化品 |
| 1,2-Dichloroethane, 99.5%, SuperDry, water≤30 ppm, J&Kseal 1,2-二氯乙烷 | 107-06-2 | 991050促 危化品 |
| 1,4-Dioxane, 99.5%, SuperDry, with molecular sieves, stabilized with BHT, J&Kseal, water≤50 ppm 1,4-二氧六环 | 123-91-1 | 972869促 危化品 |
核磁检测试剂
| 品名 | CAS | 货号 |
|---|---|---|
| Dimethyl sulfoxide-d6, 99.8 atom%D, contains 0.03% v/v TMS 氘代二甲基亚砜-d6 | 2206-27-1 | 182473促 |
| Chloroform-d, 99.8 atom%D, contains 0.03% v/v TMS, packed in 10*0.6 ml ampoules 氘代氯仿 | 865-49-6 | 240987促 |
| Tetrahydrofuran-d8, 99.5 atom%D 氘代四氢呋喃-d8 | 1693-74-9 | 247731 |
| Acetonitrile-d3, 99.8 atom%D 氘代乙腈-d3 | 2206-26-0 | 236920促 |
| Dichloromethane-d2, 99.8 atom%D 氘代二氯甲烷 | 1665-00-5 | 334919促 |
| Methanol-d4, 99.8 atom%D 氘代甲醇-d4 | 811-98-3 | 114655促 |
耗材
| 品名 | CAS | 货号 |
|---|---|---|
| TLC silica gel plate (fluorescent indicator), GF254, layer thickness 0.2-0.25 mm, 100*100 mm, 80 pcs/pack 薄层色谱硅胶板(含荧光) | / | 983347 |
| Silica, powder, 200 mesh 硅胶 | 112945-52-5 | 227600 |
| Spotting capillary tube, I.D.:0.3mm, Length:100mm, 1000pcs/pack 玻璃点样毛细管 | / | 2734477 |
| 5 mm NMR Economy Sample Tube w/ Cap, 7″, High-Throughput 5毫米，高通量经济型核磁管，7英寸 | / | 1001281 |
| Digital stainless steel hotplate magnetic stirrer, with heating, heating temperature range: RT 340℃, power 550 W 数显不锈钢加热磁力搅拌器 | / | 1122416 |
| Magnetic stir bar, PTFE-coated, egg-shaped, A100 (6*10mm), 5 pcs/pack 聚四氟乙烯磁力搅拌子,椭圆型 | / | 1482821 |
相关阅读
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冯小明院士科研成果 | 冯氏手性双氮氧配体&催化剂——广谱性强、立体选择性好
