金属催化剂前体系列 | 不对称催化金属中心原料全品类
2026-09-17 · 推荐产品 · 百灵威授权转载
在不对称金属催化体系中，手性配体是选择性调控的核心，而金属催化剂前体则是催化活性的基础载体 —— 金属的纯度、价态、配位环境与阴离子类型，会直接影响活性物种的生成效率、反应速率乃至立体选择性。
对于不对称氢化、交叉偶联、C-H 活化、环加成等不同反应，需要匹配不同价态、不同配位数的金属前体：从零价的烯烃配合物、二价金属盐，到多核羰基配合物、环戊二烯基配合物，品类选择直接决定催化体系的适配性。
本系列汇集不对称合成领域常用的钯、铑、钌、铱、金、铜、镍、锆等全品类金属催化剂前体，严格控制金属纯度与杂质含量，涵盖盐类、羰基化合物、烯烃配合物、二聚体等多种形态，批次均一、性能稳定，可与各类手性配体原位组装催化体系，也可直接用于催化剂制备，满足从经典不对称反应到前沿特色方法学的多样化需求。
钯系催化剂前体
| 品名 | CAS | 货号 |
|---|---|---|
| Palladium(II) acetate, min. 98% (99.9+%-Pd) 醋酸钯(II) | 3375-31-3 | 46-1780促 |
| Palladium(II) chloride, 99.9%, 59.8% Pd 氯化钯(II) | 7647-10-1 | 257707 |
| Tris(dibenzylideneacetone)dipalladium(0), 98%, ≥22.7% (as Pd) 三(二亚苄基丙酮)二钯(0) | 51364-51-3 | 963490 |
| Tetrakis(triphenylphosphine)palladium(0), 99% (99.9+%-Pd) 四(三苯基膦)钯 | 14221-01-3 | 46-2150 |
| Bis(dibenzylideneacetone)palladium, 98% 双(二亚苄基丙酮)钯(0) | 32005-36-0 | 141541 |
| 1,1'-Bis(diphenylphosphino)ferrocene palladium(II)chloride dichloromethane complex, 97% 1,1'-双(二苯膦基)二茂铁二氯化钯(II)二氯甲烷复合物 | 95464-05-4 | 811200 |
| Bis(acetylacetonato)palladium(II), 99% 双(乙酰丙酮)钯(II) | 14024-61-4 | 479131 |
| Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, min. 98% 四(乙腈)四氟硼酸钯(II) | 21797-13-7 | 46-2145 |
| Allylpalladium(II) chloride dimer, 98% 氯化烯丙基钯(II)二聚物 | 12012-95-2 | 982398 |
| Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct, 98% 三(二亚苄基丙酮)二钯(0)-氯仿加合物 | 52522-40-4 | 357699 |
| Sodium tetrachloropalladate(II), 99.9%, 36% Pd 四氯钯酸(II)钠 | 13820-53-6 | 132187 |
| Palladium(II) trifluoroacetate, 32% Pd 三氟乙酸钯(II) | 42196-31-6 | 450751 |
| Tris(dibenzylideneacetone)dipalladium(0), 98%, 17.5 - 23.2% Pd 三(二亚苄基丙酮)二钯(0) | 51364-51-3 | 141542 |
| Dichlorobis(benzonitrile)palladium(II), 98% 双(苄腈)二氯化钯(II) | 14220-64-5 | 411434 |
| Dichloro(1,5-cyclooctadiene)palladium(II), 99% (1,5-环辛二烯)二氯化钯(II) | 12107-56-1 | 607604 |
| Chloro(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2-amino-1,1'-biphenyl-2-yl)palladium(II), 98% 氯(2-二环己基膦基-2',6'-二-异丙氧基-1,1'-联苯基)(2-氨基-1,1'-联苯-2-基)钯(II) | 1375325-68-0 | 1484800新 |
| Di-μ-chlorobis[(1,2,3-≈)-1-phenyl-2-propenyl]dipalladium(II), 98% 二-双[(1,2,3)-1-苯基- 2 -丙烯]二钯(II),98% | 12131-44-1 | 46-0295 |
| Palladium(II) nitrate hydrate (Pd ~40%) (99.9%-Pd) 硝酸钯水合物 | 207596-32-5 | 93-4608 |
| Pd(amphos)Cl2, 98% 双[二叔丁基-(4-二甲基氨基苯基)膦]二氯化钯(II) | 887919-35-9 | 944835 |
| (2'-Methylamino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer, min. 98% （2'-甲氨基-1,1'-联苯-2-基）甲磺酰钯（II）二聚体， 98％ | 1581285-85-9 | 46-1553促 |
| Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II), min. 98% [XPhos Palladacycle Gen. 2] 氯（2-二环己基膦基-2',4',6'-三-异丙基-1,1'-联苯基）（2'-氨基-1，1'-联苯-2-基）钯（II） | 1310584-14-5 | 46-0281 |
| Palladium(II) trimethylacetate, 98% 三甲基醋酸钯(II) | 106224-36-6 | 1094128 |
| Chloro(2-Dicyclohexylphosphino-2,6-di-i-Propoxy-1,1-Biphenyl)[2-(2-Aminoethylphenyl)]Palladium(II), 98% 氯(2-二环己膦基-2,6-二I-丙氧基-1,1-联苯)[2-(2-氨基乙基苯基)]钯(Ⅱ) | 1028206-60-1 | 904240 |
| Palladium(II) bromide, 99% 溴化钯 | 13444-94-5 | 373191 |
| Methanesulfonato(tri-t-butylphosphino)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), 98% [P(t-Bu)₃ Palladacycle Gen. 4] 甲磺酸(三叔丁基膦基)(2'-甲氨基-1,1'-联苯-2-基)钯(II) | 1621274-11-0 | 46-0385 |
| Methanesulfonato(diadamantyl-n-butylphosphino)-2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min. 95% [cataCXium® A Palladacycle Gen. 3] 甲磺酸根(二金刚烷基-正丁基膦基)-2'-氨基-1,1'-联苯-2-基)钯(II)二氯甲烷加合物 | 1651823-59-4 | 46-0278 |
| Allylchloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]palladium(II), 98% 烯丙基氯化[1,3-双(2,6-二异丙基苯)咪唑-2-基]钯 | 478980-03-9 | 903057新 |
| Methanesulfonato(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct min. 98% [SPhos Palladacycle Gen. 4] 甲烷磺酸(2-二环己基膦基-2',6'-二甲氧基-1,1'-联苯基)(2'-甲氨基-1,1'-联苯-2-基)钯(II) 二氯甲烷加合物 | 1599466-87-1 | 46-0380 |
铑系催化剂前体
| 品名 | CAS | 货号 |
|---|---|---|
| Rhodium(III) chloride, 98% 氯化铑(III) | 10049-07-7 | 398503 |
| Rhodium(III) chloride hydrate, 99.9% 氯化铑(III)水合物 | 20765-98-4 | 197300 |
| Rhodium(III) Chloride Trihydrate 三氯化铑(III)三水合物 | 13569-65-8 | SY113105 |
| Chlorodicarbonylrhodium(I) dimer, 98% 二羰基氯化铑(I) 二聚体 | 14523-22-9 | 249130 |
| Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 24% Rh 双(1,5-环辛二烯)四氟硼酸铑(I) | 35138-22-8 | 938877 |
| Rhodium(III) acetylacetonate, 97% 乙酰丙酮铑(III) | 14284-92-5 | 456301 |
| Rhodium acetate, 40% Rh 醋酸铑 | 42204-14-8 | 407678 |
| Chloro(1,5-cyclooctadiene)rhodium(I) dimer, 98% (1,5-环辛二烯)氯化铑(I)二聚体 | 12092-47-6 | 500156 |
| Rhodium(II) trifluoroacetate dimer, 99%, for synthesis 三氟乙酸铑(II)二聚体 | 31126-95-1 | 919172 |
| Rhodium(II) acetate dimer, 99%, anhydrous, 46% Rh 乙酸铑(II)二聚体 | 15956-28-2 | 163176 |
| Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer, 96% 氯降冰片二烯铑二聚体 | 12257-42-0 | 253609 |
| Chlorobis(cyclooctene)rhodium(I) Dimer 双(环辛烯)氯化铑(I)二聚体 | 12279-09-3 | C2253 |
| (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer (五甲基环戊二烯基)五氯化铑(III)二聚体 | 12354-85-7 | P1788 |
| Tris(triphenylphosphine)rhodium(I) chloride, 98% 三(三苯基膦)氯化铑(I) | 14694-95-2 | 901667 |
| Dicarbonyl-acetylacetonato-rhodium(I), 98%, ≥39.05% Rh 二羰基乙酰丙酮铑(I) | 14874-82-9 | 988415 |
| Rhodium(II) Octanoate Dimer 辛酸铑(II)二聚体 | 73482-96-9 | R0161 |
| Chlorobis(ethylene)rhodium(I) dimer, 99% 二(乙烯)氯铑二聚体 | 12081-16-2 | 45-0270促 |
| 硝酸铑(III) 水合物 硝酸铑(III) 水合物 | 10139-58-9 | 83750 危化品 |
| Rhodium(III) bromide dihydrate 二水溴化铑 | 15608-29-4 | 45-1876 |
钌系催化剂前体
| 品名 | CAS | 货号 |
|---|---|---|
| Ruthenium(III) chloride hydrate, 99.9%, for synthesis 三氯化钌(III)水合物 | 14898-67-0 | 961642 |
| Tris(2,2'-bipyridyl)ruthenium(II)chloride hexahydrate, 98% 三(2,2’-联吡啶基)氯化钌(II)六水合物 | 50525-27-4 | 102033 |
| Grubbs Catalyst 2nd Generation 第二代格拉布催化剂 | 246047-72-3 | SY010577 |
| Ruthenium(III) acetylacetonate, 25% Ru 乙酰丙酮钌(III) | 14284-93-6 | 299291 |
| Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium (II) dichloride 三( 4,7-联苯-1,10-邻菲啰啉)二氯化钌 | 36309-88-3 | 241557 |
| Dichloro(p-cymene)ruthenium(II) dimer, 33% Ru 二氯(对甲基异丙苯)钌(II) 二聚体 | 52462-29-0 | 999889 |
| Ruthenium(IV) oxide hydrate, 54% Ru 氧化钌(IV)水合物 | 32740-79-7 | 346088 |
| Tris(2,2'-bipyridine)ruthenium(II) bis(hexafluorophosphate), 98% 三(2,2'-联吡啶)钌(II)二(六氟磷酸)盐 | 60804-74-2 | 988227 |
| Tetrapropylammonium perruthenate, 97%, for synthesis 四丙基高钌酸铵 | 114615-82-6 | 958987 |
| Benzeneruthenium(II) chloride dimer, 97% 苯基氯化钌(II)二聚体 | 37366-09-9 | 283313 |
| Umicore M1, 10% Ru, Product of Umicore (3-苯基-1H-茚-1-亚基)双(三环己基膦)二氯化钌(II) | 250220-36-1 | 284990 |
| Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), 98%, Ru≥31% 双(2-甲基烯丙基)(1,5-环辛二烯)钌(II) | 12289-94-0 | 954589 |
| Ruthenium(III) acetate, Ru: 31.7 - 38.6% 醋酸钌(III) | 72196-32-8 | 1120803 |
| Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II), 98% 氯(五甲基环戊二烯基)(环辛二烯)钌(II) | 92390-26-6 | 498263 |
| Bis(cyclopentadienyl)ruthenium(II), 98% 双(环戊二烯)钌(II) | 1287-13-4 | 148638 |
| Chlorocarbonylhydrido[4,5-bis-(di-i-propylphosphinomethyl)acridine]ruthenium(II), min.98% Milstein Acridine Catalyst 氯羰基氢化[4,5-双-（二-异丙基膦基）吖啶]钌（II） | 1101230-25-4 | 44-0525 |
| Carbonylchlorohydrotris(triphenylphosphine)ruthenium(II), 97% 羰基氯氢三(三苯基膦)钌(II) | 16971-33-8 | 606225 |
| Ruthenium(III) bromide hydrate 水合溴化钌 | 14014-88-1 | 44-1825 |
| Tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate, min. 98% 三(丙腈基)伍甲基环戊二烯基钌 (II) 六氟磷酸 | 99604-67-8 | 44-7880 |
| Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II) 碳酰(二氢)三(三苯基膦)钌(II) | 25360-32-1 | C2251 |
| Umicore M51, 15% Ru, Product of Umicore Umicore M51 催化剂 | 1031262-71-1 | 1120788 |
铱系催化剂前体
| 品名 | CAS | 货号 |
|---|---|---|
| Iridium(III) chloride hydrate, 50 - 58% Ir 三氯化铱(III)水合物 | 14996-61-3 | 110534 |
| Iridium(III) chloride, Ir≥63.9% 氯化铱 | 10025-83-9 | 997634 |
| Chloro(1,5-cyclooctadiene)iridium(I) dimer, 98% 1,5-环辛二烯氯化铱(I)二聚体 | 12112-67-3 | 192969 |
| (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[[5-trifluoromethyl-2-pyridinyl-kappaN)phenyl-kappaC]iridium(III) Hexafluorophosphate, 95% (4,4'-二叔丁基-2,2'-联吡啶)双[3,5-二氟-2-[[5-三氟甲基-2-吡啶基-κN]苯基-κC]铱(III)六氟磷酸盐 | 870987-63-6 | 1866865 |
| Tris(2-phenylpyridine)iridium, 99%, for synthesis 三(2-苯基吡啶)合铱 | 94928-86-6 | 997766 |
| [Ir(dtbbpy)(ppy)2]PF6, 97% (4,4'-二叔丁基-2,2'-联吡啶)双[(2-吡啶基)苯基]铱(III)六氟磷酸盐 | 676525-77-2 | 1836092 |
| Pentamethylcyclopentadienyliridium(III) chloride dimer, 98% (五甲基环戊二烯基)氯化铱(III)二聚体 | 12354-84-6 | 283094 |
| (2,2'-Bipyridine)bis[3,5-difluoro-2-[[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99% （2,2'-联吡啶）双[3,5-二氟-2- [[5-三氟甲基-2-吡啶基-kN]苯基-kC]六氟磷酸铱（III），99％ | 1092775-62-6 | 77-0453促 |
金系催化剂前体
| 品名 | CAS | 货号 |
|---|---|---|
| Gold(III) chloride hydrate, reagent grade, Au ≥ 47.5% 四氯金(III)酸水合物 | 27988-77-8 | 930848 |
| Chlorotriphenylphosphinegold(I), 98% 三苯基膦氯化金(I) | 14243-64-2 | 406825 |
| Chloro(dimethylsulfide)gold(I), 97% 氯(二甲基硫化)金(I) | 29892-37-3 | 512896 |
| Triphenylphosphinegold(I) bis(trifluoromethanesulfonyl)imidate, 98% 三苯基膦金(I)双(三氟甲磺酰基)亚胺盐 | 866395-16-6 | 1415906 |
| Gold(III) chloride, 99% (99.9%-Au) 氯化金 | 13453-07-1 | 93-7907 |
| Potassium Tetrachloroaurate(III) 氯金酸钾(III) | 13682-61-6 | SY068967 |
| Chloro[(1,1′-biphenyl-2-yl)di-tert-butylphosphine]gold(I), 98% 氯[2-(二叔丁基磷)二苯基]金 | 854045-93-5 | 789218 |
其他非贵金属金属前体
| 品名 | CAS | 货号 |
|---|---|---|
| Copper(II) acetate monohydrate, 98%, for synthesis 一水合醋酸铜 | 6046-93-1 | 358729 |
| Copper(II) trifluoromethanesulfonate, 98%, for synthesis 三氟甲烷磺酸铜(II) | 34946-82-2 | 902922 |
| Nickel(II) bromide, dimethoxyethane adduct, min. 97% 乙二醇二甲醚溴化镍 | 28923-39-9 | 28-1145 |
| Nickel(II) chloride hexahydrate, 99.9% 氯化镍(II)六水合物 | 7791-20-0 | 486536 |
| Nickel(II) iodide, anhydrous (99.5%-Ni) 无水碘化镍(II)(99.5%-Ni) | 13462-90-3 | 93-2827促 |
| Nickel(II) chloride, anhydrous, 98% 无水氯化镍 | 7718-54-9 | 93-2809 危化品 |
| Bis(cyclopentadienyl)zirconium dichloride, 98.5% 双(环戊二烯)二氯化锆 | 1291-32-3 | 502144 |
超干溶剂
| 品名 | CAS | 货号 |
|---|---|---|
| Tetrahydrofuran, 99.9%, SuperDry, stabilized with 250 ppm BHT, Water≤50 ppm, J&KSeal 四氢呋喃 | 109-99-9 | 315353促 危化品 |
| Acetonitrile, 99.9%, SuperDry, with molecular sieves, water≤50 ppm, J&KSeal 乙腈 | 75-05-8 | 939631促 危化品 |
| 1,2-Dichloroethane, 99.5%, SuperDry, water≤30 ppm, J&Kseal 1,2-二氯乙烷 | 107-06-2 | 991050促 危化品 |
| 1,4-Dioxane, 99.5%, SuperDry, with molecular sieves, stabilized with BHT, J&Kseal, water≤50 ppm 1,4-二氧六环 | 123-91-1 | 972869促 危化品 |
核磁检测试剂
| 品名 | CAS | 货号 |
|---|---|---|
| Dimethyl sulfoxide-d6, 99.8 atom%D, contains 0.03% v/v TMS 氘代二甲基亚砜-d6 | 2206-27-1 | 182473促 |
| Chloroform-d, 99.8 atom%D, contains 0.03% v/v TMS, packed in 10*0.6 ml ampoules 氘代氯仿 | 865-49-6 | 240987促 |
| Tetrahydrofuran-d8, 99.5 atom%D 氘代四氢呋喃-d8 | 1693-74-9 | 247731 |
| Acetonitrile-d3, 99.8 atom%D 氘代乙腈-d3 | 2206-26-0 | 236920促 |
| Dichloromethane-d2, 99.8 atom%D 氘代二氯甲烷 | 1665-00-5 | 334919促 |
| Methanol-d4, 99.8 atom%D 氘代甲醇-d4 | 811-98-3 | 114655促 |
耗材
| 品名 | CAS | 货号 |
|---|---|---|
| TLC silica gel plate (fluorescent indicator), GF254, layer thickness 0.2-0.25 mm, 100*100 mm, 80 pcs/pack 薄层色谱硅胶板(含荧光) | / | 983347 |
| Silica, powder, 200 mesh 硅胶 | 112945-52-5 | 227600 |
| Spotting capillary tube, I.D.:0.3mm, Length:100mm, 1000pcs/pack 玻璃点样毛细管 | / | 2734477 |
| 5 mm NMR Economy Sample Tube w/ Cap, 7″, High-Throughput 5毫米，高通量经济型核磁管，7英寸 | / | 1001281 |
| Digital stainless steel hotplate magnetic stirrer, with heating, heating temperature range: RT 340℃, power 550 W 数显不锈钢加热磁力搅拌器 | / | 1122416 |
| Magnetic stir bar, PTFE-coated, egg-shaped, A100 (6*10mm), 5 pcs/pack 聚四氟乙烯磁力搅拌子,椭圆型 | / | 1482821 |
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