金鸡纳碱 / BINOL / CBS / 硫脲 | 常用有机小分子催化剂现货
2026-09-17 · 推荐产品 · 百灵威授权转载
无金属有机小分子催化凭借环境友好、无重金属残留等优势，已成为不对称合成的重要分支。本系列覆盖主流有机小分子催化剂类型，批次稳定，可直接用于不对称催化反应筛选。
金鸡纳碱类有机催化剂
可催化不对称亲核加成、环氧化、羟基化等多种反应，是有机小分子催化的经典工具。
| 品名 | CAS | 货号 |
|---|---|---|
| Quinidine, 83% 奎尼丁 | 56-54-2 | 272633 |
| Quinine, 97%, for synthesis 奎宁 | 130-95-0 | 938232 |
| Cinchonidine, 98.5% 辛可尼丁 | 485-71-2 | 232996 |
| Cinchonine, 95% 辛可宁 | 118-10-5 | 287282 |
| Quinine hydrochloride, 99% 奎宁盐酸盐 | 130-89-2 | 561192 |
| Quinine hydrochloride dihydrate, 99% 奎宁单盐酸盐二水合物 | 6119-47-7 | 130660 |
| N-Benzylquininium chloride, 98% N-苄基奎宁鎓氯化物 | 67174-25-8 | 282966 |
| N-[(9S)-8alpha-Cinchonan-9-yl]quinoline-8-sulfonamide N-[(9S)-8α-辛可宁-9-基]喹啉-8-磺胺 | 1440939-88-7 | C2728 |
| 9-Amino-(9-deoxy)epi-quinine trihydrochloride, 98% 9-氨基-(9-脱氧)表奎宁 三盐酸盐 | 1231763-32-8 | 1278604 |
| N-[(9R)-6'-Methoxycinchonan-9-yl]-3,5-bis(trifluoromethyl)-benzenesulfonamide, 97% N-[(9R)-6'-甲氧基奎宁-9-基]-3,5-双(三氟甲基)苯亚磺酰胺 | 1096403-83-6 | 9222696 |
| Quinine sulfate, 95% 奎宁硫酸盐 | 804-63-7 | 390492 |
轴手性BINOL类有机催化剂
轴手性有机催化家族的核心成员，广泛用于Lewis酸催化、不对称氢化、Diels-Alder反应等。
| 品名 | CAS | 货号 |
|---|---|---|
| (S)-(-)-1,1'-Bi-2,2'-naphthol, 99% (S)-(-)-1,1'-联萘-2,2'-二酚 | 18531-99-2 | 465318 |
| (R)-(+)-1,1'-Bi-2,2'-naphthol, 99% (R)-(+)-1,1'-联萘-2,2'-二酚 | 18531-94-7 | 465317 |
| (R)-(+)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2,2'-naphthol, 98%, ≥99%e.e. (R)-(+)-5,5',6,6',7,7',8,8'-八氢-1,1'-联萘-2,2'-二酚 | 65355-14-8 | 938721 |
| (R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2,2'-naphthol, 95% (R)-(+)-3,3'-双(3,5-双(三氟甲基)苯基)-1,1'-联萘-2,2'-二酚 | 756491-54-0 | 789130 |
| (S)-3,3'-Bis(phenyl)-1,1'-bi-2-naphthol, 98%, ee: 99% (S)-3,3'-二苯基-1,1'-联萘酚 | 102490-05-1 | 2740665 |
| (R)-3,3'-Bis(phenyl)-1,1'-bi-2-naphthol, 98%, ee: ≥99% (R)-3,3'-二苯基-1,1'-联萘酚 | 75684-93-4 | 2740664 |
| (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate, 98% (S)-(+)-1,1'-联萘-2,2'-二基磷酸氢酯 | 35193-64-7 | 109345 |
| (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate, 98% (R)-(-)-联萘酚膦酸酯 | 39648-67-4 | 996635 |
| (S)-(+)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate, 96% (S)-3,3'-双(三苯甲硅烷基)-1,1'-联萘-2,2'-二酚磷酸酯 | 929097-92-7 | 1476982 |
| (R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate, 96% (R)-(-)-3,3'-双(三苯甲硅烷基)-1,1'-联萘-2,2'-二酚膦酸氢酯 | 791616-55-2 | 789137 |
| (R)-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-diphenyl-1,1'-phosphine oxide], 97%, ee: 98% (R)-[1,1'-联萘]-2,2'-二基双[1,1-二苯基氧膦] | 94041-16-4 | 2740685 |
| (S)-[1,1''-Binaphthalene]-2,2''-diylbis[1,1-diphenyl-1,1''-phosphine oxide], 97%, ee: 98% (S)-[1,1'-联萘]-2,2'-二基双-[1,1-二苯基氧膦] | 94041-18-6 | 2740686 |
| 2,2'-Dibromo-1,1'-binaphthyl 2,2'-二溴-1,1'-联萘 | 74866-28-7 | D4221 |
| (S)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthyl, 98% (S)-2,2'-双(甲氧基甲氧基)-1,1'-联萘 | 142128-92-5 | 449015 |
| (R)-2,2'-Dibromo-1,1'-binaphthalene, 97%, ee: 98% (R)-2,2'-二溴-1,1'-联萘酚 | 86688-08-6 | 632908 |
| (R)-2,2''-Bis(bromomethyl)-1,1''-binaphthalene, 97%, ee: 98% (R)-2,2''-双(溴甲基)-1,1''-双萘 | 86631-56-3 | 1737525 |
| (S)-2,2'-Bis(bromomethyl)-1,1'-binaphthalene, 97%, ee: 98% (S)-2,2'-二(溴甲基)-1,1'-联萘 | 37803-02-4 | 2743035 |
| (R)-N,N'-Dimethyl-1,1'-binaphthyldiamine, 97% (R)-N,N'-二甲基-1,1'-联萘二胺 | 93713-30-5 | 807287 |
CBS类有机催化剂
用于酮的不对称硼烷还原，是手性醇合成的重要工具。
| 品名 | CAS | 货号 |
|---|---|---|
| (R)-2-Methyl-CBS-oxazaborolidine, 97% (R)-2-甲基-CBS-恶唑硼烷 | 112022-83-0 | 913741 |
| (S)-(-)-2-Methyl-CBS-oxazaborolidine, 1.0 M solution in THF (S)-(-)-2-甲基-CBS-噁唑硼烷 | 112022-81-8 | 107724 |
其他有机小分子催化剂
包含脯氨酸类、手性硫脲等，通过烯胺/亚胺离子机制或氢键协同活化，用于不对称Aldol、Mannich、Michael加成、Henry反应等。
| 品名 | CAS | 货号 |
|---|---|---|
| L-Proline, 99% L-脯氨酸 | 147-85-3 | 132204 |
| D-Proline, 99% D-脯氨酸 | 344-25-2 | 211433 |
| 1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1R,2R)-2-(dimethylamino)cyclohexyl]thiourea, 97% 1-(3,5-双(三氟甲基)苯基)-3-((1R,2R)-2-(二甲基氨基)环己基)硫脲 | 620960-26-1 | 790267 |
超干溶剂
| 品名 | CAS | 货号 |
|---|---|---|
| Tetrahydrofuran, 99.9%, SuperDry, stabilized with 250 ppm BHT, Water≤50 ppm, J&KSeal 四氢呋喃 | 109-99-9 | 315353促 危化品 |
| Acetonitrile, 99.9%, SuperDry, with molecular sieves, water≤50 ppm, J&KSeal 乙腈 | 75-05-8 | 939631促 危化品 |
| 1,2-Dichloroethane, 99.5%, SuperDry, water≤30 ppm, J&Kseal 1,2-二氯乙烷 | 107-06-2 | 991050促 危化品 |
| 1,4-Dioxane, 99.5%, SuperDry, with molecular sieves, stabilized with BHT, J&Kseal, water≤50 ppm 1,4-二氧六环 | 123-91-1 | 972869促 危化品 |
核磁检测试剂
| 品名 | CAS | 货号 |
|---|---|---|
| Dimethyl sulfoxide-d6, 99.8 atom%D, contains 0.03% v/v TMS 氘代二甲基亚砜-d6 | 2206-27-1 | 182473促 |
| Chloroform-d, 99.8 atom%D, contains 0.03% v/v TMS, packed in 10*0.6 ml ampoules 氘代氯仿 | 865-49-6 | 240987促 |
| Tetrahydrofuran-d8, 99.5 atom%D 氘代四氢呋喃-d8 | 1693-74-9 | 247731 |
| Acetonitrile-d3, 99.8 atom%D 氘代乙腈-d3 | 2206-26-0 | 236920促 |
| Dichloromethane-d2, 99.8 atom%D 氘代二氯甲烷 | 1665-00-5 | 334919促 |
| Methanol-d4, 99.8 atom%D 氘代甲醇-d4 | 811-98-3 | 114655促 |
耗材
| 品名 | CAS | 货号 |
|---|---|---|
| TLC silica gel plate (fluorescent indicator), GF254, layer thickness 0.2-0.25 mm, 100*100 mm, 80 pcs/pack 薄层色谱硅胶板(含荧光) | / | 983347 |
| Silica, powder, 200 mesh 硅胶 | 112945-52-5 | 227600 |
| Spotting capillary tube, I.D.:0.3mm, Length:100mm, 1000pcs/pack 玻璃点样毛细管 | / | 2734477 |
| 5 mm NMR Economy Sample Tube w/ Cap, 7″, High-Throughput 5毫米，高通量经济型核磁管，7英寸 | / | 1001281 |
| Digital stainless steel hotplate magnetic stirrer, with heating, heating temperature range: RT 340℃, power 550 W 数显不锈钢加热磁力搅拌器 | / | 1122416 |
| Magnetic stir bar, PTFE-coated, egg-shaped, A100 (6*10mm), 5 pcs/pack 聚四氟乙烯磁力搅拌子,椭圆型 | / | 1482821 |
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