格氏试剂：构筑碳-碳键的“全能工具”，百灵威现货矩阵一站配齐
2026-09-07 · 推荐产品 · 百灵威授权转载
一个多世纪以来，格氏试剂一直是有机合成中构筑碳-碳键最经典、最可靠的工具之一。从药物活性分子到农药中间体，从精细化学品到功能材料，格氏反应的身影无处不在——它是化学家手中用途最广、反应最直接的碳链构建手段。
2025-2026年，格氏试剂的应用正迎来两股新浪潮：一是绿色溶剂替代——2-甲基四氢呋喃（2-MeTHF）和环戊基甲醚（CPME）等生物可再生溶剂正逐步取代传统四氢呋喃，提升了格氏试剂在多种医药中间体合成中的稳定性和产率；二是连续流工艺放大——微反应器技术被成功用于强放热的格氏反应，解决了传统批式合成的安全瓶颈，实现了更高效的工业生产。
无论您是在医药研发中构建复杂药物骨架，在农药创制中合成关键中间体，还是在精细化工领域开发新化合物，格氏试剂都是您工具箱中不可或缺的“万能钥匙”。
从经典反应到绿色创新工艺，格氏试剂持续赋能化学合成。百灵威格氏试剂现货矩阵，助您高效构筑碳-碳键。
格氏试剂
| 品名 | CAS | 货号 |
|---|---|---|
| Cyclohexylmagnesium chloride, 2.0 M solution in 2-MeTHF, J&KSeal 环己基氯化镁 | 931-51-1 | 944820促 |
| Phenylmagnesium chloride, 2.0 M solution in THF, J&KSeal 苯基氯化镁 | 100-59-4 | 109677促 |
| tert-Butylmagnesium chloride, 1.0 M solution in THF, J&KSeal 叔丁基氯化镁 | 677-22-5 | 120466促 |
| Allylmagnesium chloride, 1.7 M solution in THF, J&KSeal 烯丙基氯化镁 | 2622-05-1 | 356369 |
| Ethylmagnesium bromide, 3.0 M solution in diethyl ether, J&KSeal 乙基溴化镁 | 925-90-6 | 942167促 |
| Isopropylmagnesium chloride, 2.0 M solution in THF, J&KSeal 异丙基氯化镁 | 1068-55-9 | 153900促 |
| Isopropylmagnesium chloride-lithium chloride complex, 1.3 M solution in THF, J&KSeal 异丙基氯化镁-氯化锂络合物 | 745038-86-2 | 524459促 |
| Phenylmagnesium bromide, 2.9 M solution in 2-MeTHF, J&KSeal 溴化苯基镁 | 100-58-3 | 968141促 危化品 |
| Methylmagnesium bromide, 3.0 M solution in diethyl ether, J&KSeal 甲基溴化镁 | 75-16-1 | 917218促 危化品 |
| n-Butylmagnesium chloride, 2.0 M solution in THF, J&KSeal 正丁基氯化镁 | 693-04-9 | 177368促 |
| Pentylmagnesium chloride, 2.0 M solution in THF, J&KSeal 戊基氯化镁 | 6393-56-2 | 343268 |
| 2-Mesitylmagnesium bromide, 1.0 M solution in THF, J&KSeal 2-均三甲苯基溴化镁 | 2633-66-1 | 914974促 |
| 4-Methoxyphenylmagnesium bromide, 0.5 M solution in THF, J&KSeal 4-甲氧基苯基溴化镁 | 13139-86-1 | 498418 |
| 1-Methyl-1-propenylmagnesium bromide, 0.5 M solution in THF, J&KSeal 1-甲基-1-丙烯基溴化镁 | 85676-85-3 | 552634促 |
| 4-Fluoro-2-methylphenylmagnesium bromide, 0.5 M solution in THF, J&Kseal 4-氟-2-甲苯基溴化镁 | 30897-90-6 | 565492 |
| 4-(N,N-Dimethyl)aniline magnesium bromide, 0.5 M solution in THF, J&Kseal 4-(N,N-二甲基)苯胺溴化镁 | 7353-91-5 | 598450 |
| 3-Fluoro-4-methylphenylmagnesium bromide, 0.5 M solution in THF, J&Kseal 3-氟-4-甲苯基溴化镁 | 185077-02-5 | 621241 |
| Tert-butylmagnesium chloride, 2.0 M solution in 2-MeTHF, J&KSeal 叔丁基氯化镁 | 677-22-5 | 902617 |
| 3-Methoxyphenylmagnesium bromide, 1.0 M solution in THF, J&KSeal 3-甲氧基苯基溴化镁 | 36282-40-3 | 933621 |
| Cyclopentylmagnesium chloride, 2M in THF 环戊基氯化镁 | 32916-51-1 | 982801 |
过渡金属催化剂
| 品名 | CAS | 货号 |
|---|---|---|
| 1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride, 98% [1,1'-双(二苯基膦)二茂铁]二氯化钯 | 72287-26-4 | 130100 |
| Dichlorobis(tricyclohexylphosphine)palladium(II), 98% 双(三环己基膦)二氯化钯(II) | 29934-17-6 | 195061 |
| Tris(dibenzylideneacetone)dipalladium(0), 98%, ≥22.7% (as Pd) 三(二亚苄基丙酮)二钯(0) | 51364-51-3 | 963490 |
| 1,3-Bis(diphenylphosphino)propane nickel(II) chloride, 99% 1,3-双(二苯基膦)丙烷氯化镍(II) | 15629-92-2 | 285821 |
| Nickel(II) chloride hexahydrate, 99.9% 氯化镍(II)六水合物 | 7791-20-0 | 486536 |
超干溶剂
| 品名 | CAS | 货号 |
|---|---|---|
| 2-Methyltetrahydrofuran, 99%, SuperDry, water≤20 ppm, J&KSeal 2-甲基四氢呋喃 | 96-47-9 | 284814促 危化品 |
| Cyclopentyl methyl ether, 99.5%, SuperDry, stabilized with BHT, J&KSeal 环戊基甲基醚 | 5614-37-9 | 459276 |
| Tetrahydrofuran, 99.9%, SuperDry, stabilized with 250 ppm BHT, Water≤50 ppm, J&KSeal 四氢呋喃 | 109-99-9 | 315353促 危化品 |
| 1,4-Dioxane, 99.5%, SuperDry, with molecular sieves, stabilized with BHT, J&Kseal, water≤50 ppm 1,4-二氧六环 | 123-91-1 | 972869促 危化品 |
| 1,2-Dimethoxyethane, 99.5%, SuperDry, water≤30 ppm, J&KSeal 1,2-二甲氧基乙烷 | 110-71-4 | 961681促 危化品 |
| Methyl tert-butyl ether, 99%, SuperDry, with molecular sieves, Water≤30 ppm, J&Kseal 甲基叔丁基醚 | 1634-04-4 | 932542促 危化品 |
核磁检测试剂
| 品名 | CAS | 货号 |
|---|---|---|
| Dimethyl sulfoxide-d6, 99.8 atom%D, contains 0.03% v/v TMS 氘代二甲基亚砜-d6 | 2206-27-1 | 182473促 |
| Chloroform-d, 99.8 atom%D, contains 0.03% v/v TMS, packed in 10*0.6 ml ampoules 氘代氯仿 | 865-49-6 | 240987促 |
| Tetrahydrofuran-d8, 99.5 atom%D 氘代四氢呋喃-d8 | 1693-74-9 | 247731 |
| Acetonitrile-d3, 99.8 atom%D 氘代乙腈-d3 | 2206-26-0 | 236920促 |
| Dichloromethane-d2, 99.8 atom%D 氘代二氯甲烷 | 1665-00-5 | 334919促 |
| Methanol-d4, 99.8 atom%D 氘代甲醇-d4 | 811-98-3 | 114655促 |
耗材
| 品名 | CAS | 货号 |
|---|---|---|
| TLC silica gel plate (fluorescent indicator), GF254, layer thickness 0.2-0.25 mm, 100*100 mm, 80 pcs/pack 薄层色谱硅胶板(含荧光) | / | 983347 |
| Silica, powder, 200 mesh 硅胶 | 112945-52-5 | 227600 |
| Spotting capillary tube, I.D.:0.3mm, Length:100mm, 1000pcs/pack 玻璃点样毛细管 | / | 2734477 |
| 5 mm NMR Economy Sample Tube w/ Cap, 7″, High-Throughput 5毫米，高通量经济型核磁管，7英寸 | / | 1001281 |
| Digital stainless steel hotplate magnetic stirrer, with heating, heating temperature range: RT 340℃, power 550 W 数显不锈钢加热磁力搅拌器 | / | 1122416 |
| Magnetic stir bar, PTFE-coated, egg-shaped, A100 (6*10mm), 5 pcs/pack 聚四氟乙烯磁力搅拌子,椭圆型 | / | 1482821 |
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